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Un poquito de la historia de las unidades del Ejército de Chile durante la Guerra del Pacífico:
Esta unidad nace como unidad de línea para enfrentar la guerra del Pacifico, pero en vez de número, tenía nombre. Su primer comandante, el coronel Pedro Lagos, fue el encargado de formar a esta brava unidad. En marzo de 1879, en su primera revista de comisario, el contingente era de solo 360 hombres.
Participa en las acciones de Los Ángeles, Tacna, Chorrillos, Miraflores, Pucará y varias expediciones en la sierra y la de Arequipa.
Desde medidos de 1881 se le otorga el N ° 5, quedando como Batallón Santiago 5° de Línea.